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rupson rotation type laboratory ball mill, capacity: 1 kg to 20 kg, | id: 12296833788

rupson rotation type laboratory ball mill, capacity: 1 kg to 20 kg, | id: 12296833788

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ball mills - an overview | sciencedirect topics

ball mills - an overview | sciencedirect topics

A ball mill is a type of grinder used to grind and blend bulk material into QDs/nanosize using different sized balls. The working principle is simple; impact and attrition size reduction take place as the ball drops from near the top of a rotating hollow cylindrical shell. The nanostructure size can be varied by varying the number and size of balls, the material used for the balls, the material used for the surface of the cylinder, the rotation speed, and the choice of material to be milled. Ball mills are commonly used for crushing and grinding the materials into an extremely fine form. The ball mill contains a hollow cylindrical shell that rotates about its axis. This cylinder is filled with balls that are made of stainless steel or rubber to the material contained in it. Ball mills are classified as attritor, horizontal, planetary, high energy, or shaker.

Grinding elements in ball mills travel at different velocities. Therefore, collision force, direction and kinetic energy between two or more elements vary greatly within the ball charge. Frictional wear or rubbing forces act on the particles, as well as collision energy. These forces are derived from the rotational motion of the balls and movement of particles within the mill and contact zones of colliding balls.

By rotation of the mill body, due to friction between mill wall and balls, the latter rise in the direction of rotation till a helix angle does not exceed the angle of repose, whereupon, the balls roll down. Increasing of rotation rate leads to growth of the centrifugal force and the helix angle increases, correspondingly, till the component of weight strength of balls become larger than the centrifugal force. From this moment the balls are beginning to fall down, describing during falling certain parabolic curves (Figure 2.7). With the further increase of rotation rate, the centrifugal force may become so large that balls will turn together with the mill body without falling down. The critical speed n (rpm) when the balls are attached to the wall due to centrifugation:

where Dm is the mill diameter in meters. The optimum rotational speed is usually set at 6580% of the critical speed. These data are approximate and may not be valid for metal particles that tend to agglomerate by welding.

The degree of filling the mill with balls also influences productivity of the mill and milling efficiency. With excessive filling, the rising balls collide with falling ones. Generally, filling the mill by balls must not exceed 3035% of its volume.

The mill productivity also depends on many other factors: physical-chemical properties of feed material, filling of the mill by balls and their sizes, armor surface shape, speed of rotation, milling fineness and timely moving off of ground product.

where b.ap is the apparent density of the balls; l is the degree of filling of the mill by balls; n is revolutions per minute; 1, and 2 are coefficients of efficiency of electric engine and drive, respectively.

A feature of ball mills is their high specific energy consumption; a mill filled with balls, working idle, consumes approximately as much energy as at full-scale capacity, i.e. during grinding of material. Therefore, it is most disadvantageous to use a ball mill at less than full capacity.

Grinding elements in ball mills travel at different velocities. Therefore, collision force, direction, and kinetic energy between two or more elements vary greatly within the ball charge. Frictional wear or rubbing forces act on the particles as well as collision energy. These forces are derived from the rotational motion of the balls and the movement of particles within the mill and contact zones of colliding balls.

By the rotation of the mill body, due to friction between the mill wall and balls, the latter rise in the direction of rotation until a helix angle does not exceed the angle of repose, whereupon the balls roll down. Increasing the rotation rate leads to the growth of the centrifugal force and the helix angle increases, correspondingly, until the component of the weight strength of balls becomes larger than the centrifugal force. From this moment, the balls are beginning to fall down, describing certain parabolic curves during the fall (Fig. 2.10).

With the further increase of rotation rate, the centrifugal force may become so large that balls will turn together with the mill body without falling down. The critical speed n (rpm) when the balls remain attached to the wall with the aid of centrifugal force is:

where Dm is the mill diameter in meters. The optimum rotational speed is usually set at 65%80% of the critical speed. These data are approximate and may not be valid for metal particles that tend to agglomerate by welding.

where db.max is the maximum size of the feed (mm), is the compression strength (MPa), E is the modulus of elasticity (MPa), b is the density of material of balls (kg/m3), and D is the inner diameter of the mill body (m).

The degree of filling the mill with balls also influences the productivity of the mill and milling efficiency. With excessive filling, the rising balls collide with falling ones. Generally, filling the mill by balls must not exceed 30%35% of its volume.

The productivity of ball mills depends on the drum diameter and the relation of drum diameter and length. The optimum ratio between length L and diameter D, L:D, is usually accepted in the range 1.561.64. The mill productivity also depends on many other factors, including the physical-chemical properties of the feed material, the filling of the mill by balls and their sizes, the armor surface shape, the speed of rotation, the milling fineness, and the timely moving off of the ground product.

where D is the drum diameter, L is the drum length, b.ap is the apparent density of the balls, is the degree of filling of the mill by balls, n is the revolutions per minute, and 1, and 2 are coefficients of efficiency of electric engine and drive, respectively.

A feature of ball mills is their high specific energy consumption. A mill filled with balls, working idle, consumes approximately as much energy as at full-scale capacity, that is, during the grinding of material. Therefore, it is most disadvantageous to use a ball mill at less than full capacity.

Milling time in tumbler mills is longer to accomplish the same level of blending achieved in the attrition or vibratory mill, but the overall productivity is substantially greater. Tumbler mills usually are used to pulverize or flake metals, using a grinding aid or lubricant to prevent cold welding agglomeration and to minimize oxidation [23].

Cylindrical Ball Mills differ usually in steel drum design (Fig. 2.11), which is lined inside by armor slabs that have dissimilar sizes and form a rough inside surface. Due to such juts, the impact force of falling balls is strengthened. The initial material is fed into the mill by a screw feeder located in a hollow trunnion; the ground product is discharged through the opposite hollow trunnion.

Cylindrical screen ball mills have a drum with spiral curved plates with longitudinal slits between them. The ground product passes into these slits and then through a cylindrical sieve and is discharged via the unloading funnel of the mill body.

Conical Ball Mills differ in mill body construction, which is composed of two cones and a short cylindrical part located between them (Fig. 2.12). Such a ball mill body is expedient because efficiency is appreciably increased. Peripheral velocity along the conical drum scales down in the direction from the cylindrical part to the discharge outlet; the helix angle of balls is decreased and, consequently, so is their kinetic energy. The size of the disintegrated particles also decreases as the discharge outlet is approached and the energy used decreases. In a conical mill, most big balls take up a position in the deeper, cylindrical part of the body; thus, the size of the balls scales down in the direction of the discharge outlet.

For emptying, the conical mill is installed with a slope from bearing to one. In wet grinding, emptying is realized by the decantation principle, that is, by means of unloading through one of two trunnions.

With dry grinding, these mills often work in a closed cycle. A scheme of the conical ball mill supplied with an air separator is shown in Fig. 2.13. Air is fed to the mill by means of a fan. Carried off by air currents, the product arrives at the air separator, from which the coarse particles are returned by gravity via a tube into the mill. The finished product is trapped in a cyclone while the air is returned in the fan.

The ball mill is a tumbling mill that uses steel balls as the grinding media. The length of the cylindrical shell is usually 11.5 times the shell diameter (Figure 8.11). The feed can be dry, with less than 3% moisture to minimize ball coating, or slurry containing 2040% water by weight. Ball mills are employed in either primary or secondary grinding applications. In primary applications, they receive their feed from crushers, and in secondary applications, they receive their feed from rod mills, AG mills, or SAG mills.

Ball mills are filled up to 40% with steel balls (with 3080mm diameter), which effectively grind the ore. The material that is to be ground fills the voids between the balls. The tumbling balls capture the particles in ball/ball or ball/liner events and load them to the point of fracture.

When hard pebbles rather than steel balls are used for the grinding media, the mills are known as pebble mills. As mentioned earlier, pebble mills are widely used in the North American taconite iron ore operations. Since the weight of pebbles per unit volume is 3555% of that of steel balls, and as the power input is directly proportional to the volume weight of the grinding medium, the power input and capacity of pebble mills are correspondingly lower. Thus, in a given grinding circuit, for a certain feed rate, a pebble mill would be much larger than a ball mill, with correspondingly a higher capital cost. However, the increase in capital cost is justified economically by a reduction in operating cost attributed to the elimination of steel grinding media.

In general, ball mills can be operated either wet or dry and are capable of producing products in the order of 100m. This represents reduction ratios of as great as 100. Very large tonnages can be ground with these ball mills because they are very effective material handling devices. Ball mills are rated by power rather than capacity. Today, the largest ball mill in operation is 8.53m diameter and 13.41m long with a corresponding motor power of 22MW (Toromocho, private communications).

Modern ball mills consist of two chambers separated by a diaphragm. In the first chamber the steel-alloy balls (also described as charge balls or media) are about 90mm diameter. The mill liners are designed to lift the media as the mill rotates, so the comminution process in the first chamber is dominated by crushing. In the second chamber the ball diameters are of smaller diameter, between 60 and 15mm. In this chamber the lining is typically a classifying lining which sorts the media so that ball size reduces towards the discharge end of the mill. Here, comminution takes place in the rolling point-contact zone between each charge ball. An example of a two chamber ball mill is illustrated in Fig. 2.22.15

Much of the energy consumed by a ball mill generates heat. Water is injected into the second chamber of the mill to provide evaporative cooling. Air flow through the mill is one medium for cement transport but also removes water vapour and makes some contribution to cooling.

Grinding is an energy intensive process and grinding more finely than necessary wastes energy. Cement consists of clinker, gypsum and other components mostly more easily ground than clinker. To minimise over-grinding modern ball mills are fitted with dynamic separators (otherwise described as classifiers or more simply as separators). The working principle is that cement is removed from the mill before over-grinding has taken place. The cement is then separated into a fine fraction, which meets finished product requirements, and a coarse fraction which is returned to mill inlet. Recirculation factor, that is, the ratio of mill throughput to fresh feed is up to three. Beyond this, efficiency gains are minimal.

For more than 50years vertical mills have been the mill of choice for grinding raw materials into raw meal. More recently they have become widely used for cement production. They have lower specific energy consumption than ball mills and the separator, as in raw mills, is integral with the mill body.

In the Loesche mill, Fig. 2.23,16 two pairs of rollers are used. In each pair the first, smaller diameter, roller stabilises the bed prior to grinding which takes place under the larger roller. Manufacturers use different technologies for bed stabilisation.

Comminution in ball mills and vertical mills differs fundamentally. In a ball mill, size reduction takes place by impact and attrition. In a vertical mill the bed of material is subject to such a high pressure that individual particles within the bed are fractured, even though the particles are very much smaller than the bed thickness.

Early issues with vertical mills, such as narrower PSD and modified cement hydration characteristics compared with ball mills, have been resolved. One modification has been to install a hot gas generator so the gas temperature is high enough to partially dehydrate the gypsum.

For many decades the two-compartment ball mill in closed circuit with a high-efficiency separator has been the mill of choice. In the last decade vertical mills have taken an increasing share of the cement milling market, not least because the specific power consumption of vertical mills is about 30% less than that of ball mills and for finely ground cement less still. The vertical mill has a proven track record in grinding blastfurnace slag, where it has the additional advantage of being a much more effective drier of wet feedstock than a ball mill.

The vertical mill is more complex but its installation is more compact. The relative installed capital costs tend to be site specific. Historically the installed cost has tended to be slightly higher for the vertical mill.

Special graph paper is used with lglg(1/R(x)) on the abscissa and lg(x) on the ordinate axes. The higher the value of n, the narrower the particle size distribution. The position parameter is the particle size with the highest mass density distribution, the peak of the mass density distribution curve.

Vertical mills tend to produce cement with a higher value of n. Values of n normally lie between 0.8 and 1.2, dependent particularly on cement fineness. The position parameter is, of course, lower for more finely ground cements.

Separator efficiency is defined as specific power consumption reduction of the mill open-to-closed-circuit with the actual separator, compared with specific power consumption reduction of the mill open-to-closed-circuit with an ideal separator.

As shown in Fig. 2.24, circulating factor is defined as mill mass flow, that is, fresh feed plus separator returns. The maximum power reduction arising from use of an ideal separator increases non-linearly with circulation factor and is dependent on Rf, normally based on residues in the interval 3245m. The value of the comminution index, W, is also a function of Rf. The finer the cement, the lower Rf and the greater the maximum power reduction. At C = 2 most of maximum power reduction is achieved, but beyond C = 3 there is very little further reduction.

Separator particle separation performance is assessed using the Tromp curve, a graph of percentage separator feed to rejects against particle size range. An example is shown in Fig. 2.25. Data required is the PSD of separator feed material and of rejects and finished product streams. The bypass and slope provide a measure of separator performance.

The particle size is plotted on a logarithmic scale on the ordinate axis. The percentage is plotted on the abscissa either on a linear (as shown here) or on a Gaussian scale. The advantage of using the Gaussian scale is that the two parts of the graph can be approximated by two straight lines.

The measurement of PSD of a sample of cement is carried out using laser-based methodologies. It requires a skilled operator to achieve consistent results. Agglomeration will vary dependent on whether grinding aid is used. Different laser analysis methods may not give the same results, so for comparative purposes the same method must be used.

The ball mill is a cylindrical drum (or cylindrical conical) turning around its horizontal axis. It is partially filled with grinding bodies: cast iron or steel balls, or even flint (silica) or porcelain bearings. Spaces between balls or bearings are occupied by the load to be milled.

Following drum rotation, balls or bearings rise by rolling along the cylindrical wall and descending again in a cascade or cataract from a certain height. The output is then milled between two grinding bodies.

Ball mills could operate dry or even process a water suspension (almost always for ores). Dry, it is fed through a chute or a screw through the units opening. In a wet path, a system of scoops that turn with the mill is used and it plunges into a stationary tank.

Mechanochemical synthesis involves high-energy milling techniques and is generally carried out under controlled atmospheres. Nanocomposite powders of oxide, nonoxide, and mixed oxide/nonoxide materials can be prepared using this method. The major drawbacks of this synthesis method are: (1) discrete nanoparticles in the finest size range cannot be prepared; and (2) contamination of the product by the milling media.

More or less any ceramic composite powder can be synthesized by mechanical mixing of the constituent phases. The main factors that determine the properties of the resultant nanocomposite products are the type of raw materials, purity, the particle size, size distribution, and degree of agglomeration. Maintaining purity of the powders is essential for avoiding the formation of a secondary phase during sintering. Wet ball or attrition milling techniques can be used for the synthesis of homogeneous powder mixture. Al2O3/SiC composites are widely prepared by this conventional powder mixing route by using ball milling [70]. However, the disadvantage in the milling step is that it may induce certain pollution derived from the milling media.

In this mechanical method of production of nanomaterials, which works on the principle of impact, the size reduction is achieved through the impact caused when the balls drop from the top of the chamber containing the source material.

A ball mill consists of a hollow cylindrical chamber (Fig. 6.2) which rotates about a horizontal axis, and the chamber is partially filled with small balls made of steel, tungsten carbide, zirconia, agate, alumina, or silicon nitride having diameter generally 10mm. The inner surface area of the chamber is lined with an abrasion-resistant material like manganese, steel, or rubber. The magnet, placed outside the chamber, provides the pulling force to the grinding material, and by changing the magnetic force, the milling energy can be varied as desired. The ball milling process is carried out for approximately 100150h to obtain uniform-sized fine powder. In high-energy ball milling, vacuum or a specific gaseous atmosphere is maintained inside the chamber. High-energy mills are classified into attrition ball mills, planetary ball mills, vibrating ball mills, and low-energy tumbling mills. In high-energy ball milling, formation of ceramic nano-reinforcement by in situ reaction is possible.

It is an inexpensive and easy process which enables industrial scale productivity. As grinding is done in a closed chamber, dust, or contamination from the surroundings is avoided. This technique can be used to prepare dry as well as wet nanopowders. Composition of the grinding material can be varied as desired. Even though this method has several advantages, there are some disadvantages. The major disadvantage is that the shape of the produced nanoparticles is not regular. Moreover, energy consumption is relatively high, which reduces the production efficiency. This technique is suitable for the fabrication of several nanocomposites, which include Co- and Cu-based nanomaterials, Ni-NiO nanocomposites, and nanocomposites of Ti,C [71].

Planetary ball mill was used to synthesize iron nanoparticles. The synthesized nanoparticles were subjected to the characterization studies by X-ray diffraction (XRD), and scanning electron microscopy (SEM) techniques using a SIEMENS-D5000 diffractometer and Hitachi S-4800. For the synthesis of iron nanoparticles, commercial iron powder having particles size of 10m was used. The iron powder was subjected to planetary ball milling for various period of time. The optimum time period for the synthesis of nanoparticles was observed to be 10h because after that time period, chances of contamination inclined and the particles size became almost constant so the powder was ball milled for 10h to synthesize nanoparticles [11]. Fig. 12 shows the SEM image of the iron nanoparticles.

The vibratory ball mill is another kind of high-energy ball mill that is used mainly for preparing amorphous alloys. The vials capacities in the vibratory mills are smaller (about 10 ml in volume) compared to the previous types of mills. In this mill, the charge of the powder and milling tools are agitated in three perpendicular directions (Fig. 1.6) at very high speed, as high as 1200 rpm.

Another type of the vibratory ball mill, which is used at the van der Waals-Zeeman Laboratory, consists of a stainless steel vial with a hardened steel bottom, and a single hardened steel ball of 6 cm in diameter (Fig. 1.7).

The mill is evacuated during milling to a pressure of 106 Torr, in order to avoid reactions with a gas atmosphere.[44] Subsequently, this mill is suitable for mechanical alloying of some special systems that are highly reactive with the surrounding atmosphere, such as rare earth elements.

In spite of the traditional approaches used for gas-solid reaction at relatively high temperature, Calka etal.[58] and El-Eskandarany etal.[59] proposed a solid-state approach, the so-called reactive ball milling (RBM), used for preparations different families of meal nitrides and hydrides at ambient temperature. This mechanically induced gas-solid reaction can be successfully achieved, using either high- or low-energy ball-milling methods, as shown in Fig.9.5. However, high-energy ball mill is an efficient process for synthesizing nanocrystalline MgH2 powders using RBM technique, it may be difficult to scale up for matching the mass production required by industrial sector. Therefore, from a practical point of view, high-capacity low-energy milling, which can be easily scaled-up to produce large amount of MgH2 fine powders, may be more suitable for industrial mass production.

In both approaches but with different scale of time and milling efficiency, the starting Mg metal powders milled under hydrogen gas atmosphere are practicing to dramatic lattice imperfections such as twinning and dislocations. These defects are caused by plastics deformation coupled with shear and impact forces generated by the ball-milling media.[60] The powders are, therefore, disintegrated into smaller particles with large surface area, where very clean or fresh oxygen-free active surfaces of the powders are created. Moreover, these defects, which are intensively located at the grain boundaries, lead to separate micro-scaled Mg grains into finer grains capable to getter hydrogen by the first atomically clean surfaces to form MgH2 nanopowders.

Fig.9.5 illustrates common lab scale procedure for preparing MgH2 powders, starting from pure Mg powders, using RBM via (1) high-energy and (2) low-energy ball milling. The starting material can be Mg-rods, in which they are processed via sever plastic deformation,[61] using for example cold-rolling approach,[62] as illustrated in Fig.9.5. The heavily deformed Mg-rods obtained after certain cold rolling passes can be snipped into small chips and then ball-milled under hydrogen gas to produce MgH2 powders.[8]

Planetary ball mills are the most popular mills used in scientific research for synthesizing MgH2 nanopowders. In this type of mill, the ball-milling media have considerably high energy, because milling stock and balls come off the inner wall of the vial and the effective centrifugal force reaches up to 20 times gravitational acceleration. The centrifugal forces caused by the rotation of the supporting disc and autonomous turning of the vial act on the milling charge (balls and powders). Since the turning directions of the supporting disc and the vial are opposite, the centrifugal forces alternately are synchronized and opposite. Therefore, the milling media and the charged powders alternatively roll on the inner wall of the vial, and are lifted and thrown off across the bowl at high speed.

In the typical experimental procedure, a certain amount of the Mg (usually in the range between 3 and 10g based on the vials volume) is balanced inside an inert gas atmosphere (argon or helium) in a glove box and sealed together with certain number of balls (e.g., 2050 hardened steel balls) into a hardened steel vial (Fig.9.5A and B), using, for example, a gas-temperature-monitoring system (GST). With the GST system, it becomes possible to monitor the progress of the gas-solid reaction taking place during the RBM process, as shown in Fig.9.5C and D. The temperature and pressure changes in the system during milling can be also used to realize the completion of the reaction and the expected end product during the different stages of milling (Fig.9.5D). The ball-to-powder weight ratio is usually selected to be in the range between 10:1 and 50:1. The vial is then evacuated to the level of 103bar before introducing H2 gas to fill the vial with a pressure of 550bar (Fig.9.5B). The milling process is started by mounting the vial on a high-energy ball mill operated at ambient temperature (Fig.9.5C).

Tumbling mill is cylindrical shell (Fig.9.6AC) that rotates about a horizontal axis (Fig.9.6D). Hydrogen gas is pressurized into the vial (Fig.9.6C) together with Mg powders and ball-milling media, using ball-to-powder weight ratio in the range between 30:1 and 100:1. Mg powder particles meet the abrasive and impacting force (Fig.9.6E), which reduce the particle size and create fresh-powder surfaces (Fig.9.6F) ready to react with hydrogen milling atmosphere.

Figure 9.6. Photographs taken from KISR-EBRC/NAM Lab, Kuwait, show (A) the vial and milling media (balls) and (B) the setup performed to charge the vial with 50bar of hydrogen gas. The photograph in (C) presents the complete setup of GST (supplied by Evico-magnetic, Germany) system prior to start the RBM experiment for preparing of MgH2 powders, using Planetary Ball Mill P400 (provided by Retsch, Germany). GST system allows us to monitor the progress of RBM process, as indexed by temperature and pressure versus milling time (D).

The useful kinetic energy in tumbling mill can be applied to the Mg powder particles (Fig.9.7E) by the following means: (1) collision between the balls and the powders; (2) pressure loading of powders pinned between milling media or between the milling media and the liner; (3) impact of the falling milling media; (4) shear and abrasion caused by dragging of particles between moving milling media; and (5) shock-wave transmitted through crop load by falling milling media. One advantage of this type of mill is that large amount of the powders (100500g or more based on the mill capacity) can be fabricated for each milling run. Thus, it is suitable for pilot and/or industrial scale of MgH2 production. In addition, low-energy ball mill produces homogeneous and uniform powders when compared with the high-energy ball mill. Furthermore, such tumbling mills are cheaper than high-energy mills and operated simply with low-maintenance requirements. However, this kind of low-energy mill requires long-term milling time (more than 300h) to complete the gas-solid reaction and to obtain nanocrystalline MgH2 powders.

Figure 9.7. Photos taken from KISR-EBRC/NAM Lab, Kuwait, display setup of a lab-scale roller mill (1000m in volume) showing (A) the milling tools including the balls (milling media and vial), (B) charging Mg powders in the vial inside inert gas atmosphere glove box, (C) evacuation setup and pressurizing hydrogen gas in the vial, and (D) ball milling processed, using a roller mill. Schematic presentations show the ball positions and movement inside the vial of a tumbler mall mill at a dynamic mode is shown in (E), where a typical ball-powder-ball collusion for a low energy tumbling ball mill is presented in (F).

ball mill - an overview | sciencedirect topics

ball mill - an overview | sciencedirect topics

The ball mill accepts the SAG or AG mill product. Ball mills give a controlled final grind and produce flotation feed of a uniform size. Ball mills tumble iron or steel balls with the ore. The balls are initially 510 cm diameter but gradually wear away as grinding of the ore proceeds. The feed to ball mills (dry basis) is typically 75 vol.-% ore and 25% steel.

The ball mill is operated in closed circuit with a particle-size measurement device and size-control cyclones. The cyclones send correct-size material on to flotation and direct oversize material back to the ball mill for further grinding.

Grinding elements in ball mills travel at different velocities. Therefore, collision force, direction and kinetic energy between two or more elements vary greatly within the ball charge. Frictional wear or rubbing forces act on the particles, as well as collision energy. These forces are derived from the rotational motion of the balls and movement of particles within the mill and contact zones of colliding balls.

By rotation of the mill body, due to friction between mill wall and balls, the latter rise in the direction of rotation till a helix angle does not exceed the angle of repose, whereupon, the balls roll down. Increasing of rotation rate leads to growth of the centrifugal force and the helix angle increases, correspondingly, till the component of weight strength of balls become larger than the centrifugal force. From this moment the balls are beginning to fall down, describing during falling certain parabolic curves (Figure 2.7). With the further increase of rotation rate, the centrifugal force may become so large that balls will turn together with the mill body without falling down. The critical speed n (rpm) when the balls are attached to the wall due to centrifugation:

where Dm is the mill diameter in meters. The optimum rotational speed is usually set at 6580% of the critical speed. These data are approximate and may not be valid for metal particles that tend to agglomerate by welding.

The degree of filling the mill with balls also influences productivity of the mill and milling efficiency. With excessive filling, the rising balls collide with falling ones. Generally, filling the mill by balls must not exceed 3035% of its volume.

The mill productivity also depends on many other factors: physical-chemical properties of feed material, filling of the mill by balls and their sizes, armor surface shape, speed of rotation, milling fineness and timely moving off of ground product.

where b.ap is the apparent density of the balls; l is the degree of filling of the mill by balls; n is revolutions per minute; 1, and 2 are coefficients of efficiency of electric engine and drive, respectively.

A feature of ball mills is their high specific energy consumption; a mill filled with balls, working idle, consumes approximately as much energy as at full-scale capacity, i.e. during grinding of material. Therefore, it is most disadvantageous to use a ball mill at less than full capacity.

The ball mill is a tumbling mill that uses steel balls as the grinding media. The length of the cylindrical shell is usually 11.5 times the shell diameter (Figure 8.11). The feed can be dry, with less than 3% moisture to minimize ball coating, or slurry containing 2040% water by weight. Ball mills are employed in either primary or secondary grinding applications. In primary applications, they receive their feed from crushers, and in secondary applications, they receive their feed from rod mills, AG mills, or SAG mills.

Ball mills are filled up to 40% with steel balls (with 3080mm diameter), which effectively grind the ore. The material that is to be ground fills the voids between the balls. The tumbling balls capture the particles in ball/ball or ball/liner events and load them to the point of fracture.

When hard pebbles rather than steel balls are used for the grinding media, the mills are known as pebble mills. As mentioned earlier, pebble mills are widely used in the North American taconite iron ore operations. Since the weight of pebbles per unit volume is 3555% of that of steel balls, and as the power input is directly proportional to the volume weight of the grinding medium, the power input and capacity of pebble mills are correspondingly lower. Thus, in a given grinding circuit, for a certain feed rate, a pebble mill would be much larger than a ball mill, with correspondingly a higher capital cost. However, the increase in capital cost is justified economically by a reduction in operating cost attributed to the elimination of steel grinding media.

In general, ball mills can be operated either wet or dry and are capable of producing products in the order of 100m. This represents reduction ratios of as great as 100. Very large tonnages can be ground with these ball mills because they are very effective material handling devices. Ball mills are rated by power rather than capacity. Today, the largest ball mill in operation is 8.53m diameter and 13.41m long with a corresponding motor power of 22MW (Toromocho, private communications).

Planetary ball mills. A planetary ball mill consists of at least one grinding jar, which is arranged eccentrically on a so-called sun wheel. The direction of movement of the sun wheel is opposite to that of the grinding jars according to a fixed ratio. The grinding balls in the grinding jars are subjected to superimposed rotational movements. The jars are moved around their own axis and, in the opposite direction, around the axis of the sun wheel at uniform speed and uniform rotation ratios. The result is that the superimposition of the centrifugal forces changes constantly (Coriolis motion). The grinding balls describe a semicircular movement, separate from the inside wall, and collide with the opposite surface at high impact energy. The difference in speeds produces an interaction between frictional and impact forces, which releases high dynamic energies. The interplay between these forces produces the high and very effective degree of size reduction of the planetary ball mill. Planetary ball mills are smaller than common ball mills, and are mainly used in laboratories for grinding sample material down to very small sizes.

Vibration mill. Twin- and three-tube vibrating mills are driven by an unbalanced drive. The entire filling of the grinding cylinders, which comprises the grinding media and the feed material, constantly receives impulses from the circular vibrations in the body of the mill. The grinding action itself is produced by the rotation of the grinding media in the opposite direction to the driving rotation and by continuous head-on collisions of the grinding media. The residence time of the material contained in the grinding cylinders is determined by the quantity of the flowing material. The residence time can also be influenced by using damming devices. The sample passes through the grinding cylinders in a helical curve and slides down from the inflow to the outflow. The high degree of fineness achieved is the result of this long grinding procedure. Continuous feeding is carried out by vibrating feeders, rotary valves, or conveyor screws. The product is subsequently conveyed either pneumatically or mechanically. They are basically used to homogenize food and feed.

CryoGrinder. As small samples (100 mg or <20 ml) are difficult to recover from a standard mortar and pestle, the CryoGrinder serves as an alternative. The CryoGrinder is a miniature mortar shaped as a small well and a tightly fitting pestle. The CryoGrinder is prechilled, then samples are added to the well and ground by a handheld cordless screwdriver. The homogenization and collection of the sample is highly efficient. In environmental analysis, this system is used when very small samples are available, such as small organisms or organs (brains, hepatopancreas, etc.).

The vibratory ball mill is another kind of high-energy ball mill that is used mainly for preparing amorphous alloys. The vials capacities in the vibratory mills are smaller (about 10 ml in volume) compared to the previous types of mills. In this mill, the charge of the powder and milling tools are agitated in three perpendicular directions (Fig. 1.6) at very high speed, as high as 1200 rpm.

Another type of the vibratory ball mill, which is used at the van der Waals-Zeeman Laboratory, consists of a stainless steel vial with a hardened steel bottom, and a single hardened steel ball of 6 cm in diameter (Fig. 1.7).

The mill is evacuated during milling to a pressure of 106 Torr, in order to avoid reactions with a gas atmosphere.[44] Subsequently, this mill is suitable for mechanical alloying of some special systems that are highly reactive with the surrounding atmosphere, such as rare earth elements.

A ball mill is a relatively simple apparatus in which the motion of the reactor, or of a part of it, induces a series of collisions of balls with each other and with the reactor walls (Suryanarayana, 2001). At each collision, a fraction of the powder inside the reactor is trapped between the colliding surfaces of the milling tools and submitted to a mechanical load at relatively high strain rates (Suryanarayana, 2001). This load generates a local nonhydrostatic mechanical stress at every point of contact between any pair of powder particles. The specific features of the deformation processes induced by these stresses depend on the intensity of the mechanical stresses themselves, on the details of the powder particle arrangement, that is on the topology of the contact network, and on the physical and chemical properties of powders (Martin et al., 2003; Delogu, 2008a). At the end of any given collision event, the powder that has been trapped is remixed with the powder that has not undergone this process. Correspondingly, at any instant in the mechanical processing, the whole powder charge includes fractions of powder that have undergone a different number of collisions.

The individual reactive processes at the perturbed interface between metallic elements are expected to occur on timescales that are, at most, comparable with the collision duration (Hammerberg et al., 1998; Urakaev and Boldyrev, 2000; Lund and Schuh, 2003; Delogu and Cocco, 2005a,b). Therefore, unless the ball mill is characterized by unusually high rates of powder mixing and frequency of collisions, reactive events initiated by local deformation processes at a given collision are not affected by a successive collision. Indeed, the time interval between successive collisions is significantly longer than the time period required by local structural perturbations for full relaxation (Hammerberg et al., 1998; Urakaev and Boldyrev, 2000; Lund and Schuh, 2003; Delogu and Cocco, 2005a,b).

These few considerations suffice to point out the two fundamental features of powder processing by ball milling, which in turn govern the MA processes in ball mills. First, mechanical processing by ball milling is a discrete processing method. Second, it has statistical character. All of this has important consequences for the study of the kinetics of MA processes. The fact that local deformation events are connected to individual collisions suggests that absolute time is not an appropriate reference quantity to describe mechanically induced phase transformations. Such a description should rather be made as a function of the number of collisions (Delogu et al., 2004). A satisfactory description of the MA kinetics must also account for the intrinsic statistical character of powder processing by ball milling. The amount of powder trapped in any given collision, at the end of collision is indeed substantially remixed with the other powder in the reactor. It follows that the same amount, or a fraction of it, could at least in principle be trapped again in the successive collision.

This is undoubtedly a difficult aspect to take into account in a mathematical description of MA kinetics. There are at least two extreme cases to consider. On the one hand, it could be assumed that the powder trapped in a given collision cannot be trapped in the successive one. On the other, it could be assumed that powder mixing is ideal and that the amount of powder trapped at a given collision has the same probability of being processed in the successive collision. Both these cases allow the development of a mathematical model able to describe the relationship between apparent kinetics and individual collision events. However, the latter assumption seems to be more reliable than the former one, at least for commercial mills characterized by relatively complex displacement in the reactor (Manai et al., 2001, 2004).

A further obvious condition for the successful development of a mathematical description of MA processes is the one related to the uniformity of collision regimes. More specifically, it is highly desirable that the powders trapped at impact always experience the same conditions. This requires the control of the ball dynamics inside the reactor, which can be approximately obtained by using a single milling ball and an amount of powder large enough to assure inelastic impact conditions (Manai et al., 2001, 2004; Delogu et al., 2004). In fact, the use of a single milling ball avoids impacts between balls, which have a remarkable disordering effect on the ball dynamics, whereas inelastic impact conditions permit the establishment of regular and periodic ball dynamics (Manai et al., 2001, 2004; Delogu et al., 2004).

All of the above assumptions and observations represent the basis and guidelines for the development of the mathematical model briefly outlined in the following. It has been successfully applied to the case of a Spex Mixer/ Mill mod. 8000, but the same approach can, in principle, be used for other ball mills.

The Planetary ball mills are the most popular mills used in MM, MA, and MD scientific researches for synthesizing almost all of the materials presented in Figure 1.1. In this type of mill, the milling media have considerably high energy, because milling stock and balls come off the inner wall of the vial (milling bowl or vial) and the effective centrifugal force reaches up to 20 times gravitational acceleration.

The centrifugal forces caused by the rotation of the supporting disc and autonomous turning of the vial act on the milling charge (balls and powders). Since the turning directions of the supporting disc and the vial are opposite, the centrifugal forces alternately are synchronized and opposite. Therefore, the milling media and the charged powders alternatively roll on the inner wall of the vial, and are lifted and thrown off across the bowl at high speed, as schematically presented in Figure 2.17.

However, there are some companies in the world who manufacture and sell number of planetary-type ball mills; Fritsch GmbH (www.fritsch-milling.com) and Retsch (http://www.retsch.com) are considered to be the oldest and principal companies in this area.

Fritsch produces different types of planetary ball mills with different capacities and rotation speeds. Perhaps, Fritsch Pulverisette P5 (Figure 2.18(a)) and Fritsch Pulverisette P6 (Figure 2.18(b)) are the most popular models of Fritsch planetary ball mills. A variety of vials and balls made of different materials with different capacities, starting from 80ml up to 500ml, are available for the Fritsch Pulverisette planetary ball mills; these include tempered steel, stainless steel, tungsten carbide, agate, sintered corundum, silicon nitride, and zirconium oxide. Figure 2.19 presents 80ml-tempered steel vial (a) and 500ml-agate vials (b) together with their milling media that are made of the same materials.

Figure 2.18. Photographs of Fritsch planetary-type high-energy ball mill of (a) Pulverisette P5 and (b) Pulverisette P6. The equipment is housed in the Nanotechnology Laboratory, Energy and Building Research Center (EBRC), Kuwait Institute for Scientific Research (KISR).

Figure 2.19. Photographs of the vials used for Fritsch planetary ball mills with capacity of (a) 80ml and (b) 500ml. The vials and the balls shown in (a) and (b) are made of tempered steel agate materials, respectively (Nanotechnology Laboratory, Energy and Building Research Center (EBRC), Kuwait Institute for Scientific Research (KISR)).

More recently and in year 2011, Fritsch GmbH (http://www.fritsch-milling.com) introduced a new high-speed and versatile planetary ball mill called Planetary Micro Mill PULVERISETTE 7 (Figure 2.20). The company claims this new ball mill will be helpful to enable extreme high-energy ball milling at rotational speed reaching to 1,100rpm. This allows the new mill to achieve sensational centrifugal accelerations up to 95 times Earth gravity. They also mentioned that the energy application resulted from this new machine is about 150% greater than the classic planetary mills. Accordingly, it is expected that this new milling machine will enable the researchers to get their milled powders in short ball-milling time with fine powder particle sizes that can reach to be less than 1m in diameter. The vials available for this new type of mill have sizes of 20, 45, and 80ml. Both the vials and balls can be made of the same materials, which are used in the manufacture of large vials used for the classic Fritsch planetary ball mills, as shown in the previous text.

Retsch has also produced a number of capable high-energy planetary ball mills with different capacities (http://www.retsch.com/products/milling/planetary-ball-mills/); namely Planetary Ball Mill PM 100 (Figure 2.21(a)), Planetary Ball Mill PM 100 CM, Planetary Ball Mill PM 200, and Planetary Ball Mill PM 400 (Figure 2.21(b)). Like Fritsch, Retsch offers high-quality ball-milling vials with different capacities (12, 25, 50, 50, 125, 250, and 500ml) and balls of different diameters (540mm), as exemplified in Figure 2.22. These milling tools can be made of hardened steel as well as other different materials such as carbides, nitrides, and oxides.

Figure 2.21. Photographs of Retsch planetary-type high-energy ball mill of (a) PM 100 and (b) PM 400. The equipment is housed in the Nanotechnology Laboratory, Energy and Building Research Center (EBRC), Kuwait Institute for Scientific Research (KISR).

Figure 2.22. Photographs of the vials used for Retsch planetary ball mills with capacity of (a) 80ml, (b) 250ml, and (c) 500ml. The vials and the balls shown are made of tempered steel (Nanotechnology Laboratory, Energy and Building Research Center (EBRC), Kuwait Institute for Scientific Research (KISR)).

Both Fritsch and Retsch companies have offered special types of vials that allow monitoring and measure the gas pressure and temperature inside the vial during the high-energy planetary ball-milling process. Moreover, these vials allow milling the powders under inert (e.g., argon or helium) or reactive gas (e.g., hydrogen or nitrogen) with a maximum gas pressure of 500kPa (5bar). It is worth mentioning here that such a development made on the vials design allows the users and researchers to monitor the progress tackled during the MA and MD processes by following up the phase transformations and heat realizing upon RBM, where the interaction of the gas used with the freshly created surfaces of the powders during milling (adsorption, absorption, desorption, and decomposition) can be monitored. Furthermore, the data of the temperature and pressure driven upon using this system is very helpful when the ball mills are used for the formation of stable (e.g., intermetallic compounds) and metastable (e.g., amorphous and nanocrystalline materials) phases. In addition, measuring the vial temperature during blank (without samples) high-energy ball mill can be used as an indication to realize the effects of friction, impact, and conversion processes.

More recently, Evico-magnetics (www.evico-magnetics.de) has manufactured an extraordinary high-pressure milling vial with gas-temperature-monitoring (GTM) system. Likewise both system produced by Fritsch and Retsch, the developed system produced by Evico-magnetics, allowing RBM but at very high gas pressure that can reach to 15,000kPa (150bar). In addition, it allows in situ monitoring of temperature and of pressure by incorporating GTM. The vials, which can be used with any planetary mills, are made of hardened steel with capacity up to 220ml. The manufacturer offers also two-channel system for simultaneous use of two milling vials.

Using different ball mills as examples, it has been shown that, on the basis of the theory of glancing collision of rigid bodies, the theoretical calculation of tPT conditions and the kinetics of mechanochemical processes are possible for the reactors that are intended to perform different physicochemical processes during mechanical treatment of solids. According to the calculations, the physicochemical effect of mechanochemical reactors is due to short-time impulses of pressure (P = ~ 10101011 dyn cm2) with shift, and temperature T(x, t). The highest temperature impulse T ~ 103 K are caused by the dry friction phenomenon.

Typical spatial and time parameters of the impactfriction interaction of the particles with a size R ~ 104 cm are as follows: localization region, x ~ 106 cm; time, t ~ 108 s. On the basis of the obtained theoretical results, the effect of short-time contact fusion of particles treated in various comminuting devices can play a key role in the mechanism of activation and chemical reactions for wide range of mechanochemical processes. This role involves several aspects, that is, the very fact of contact fusion transforms the solid phase process onto another qualitative level, judging from the mass transfer coefficients. The spatial and time characteristics of the fused zone are such that quenching of non-equilibrium defects and intermediate products of chemical reactions occurs; solidification of the fused zone near the contact point results in the formation of a nanocrystal or nanoamor- phous state. The calculation models considered above and the kinetic equations obtained using them allow quantitative ab initio estimates of rate constants to be performed for any specific processes of mechanical activation and chemical transformation of the substances in ball mills.

There are two classes of ball mills: planetary and mixer (also called swing) mill. The terms high-speed vibration milling (HSVM), high-speed ball milling (HSBM), and planetary ball mill (PBM) are often used. The commercial apparatus are PBMs Fritsch P-5 and Fritsch Pulverisettes 6 and 7 classic line, the Retsch shaker (or mixer) mills ZM1, MM200, MM400, AS200, the Spex 8000, 6750 freezer/mill SPEX CertiPrep, and the SWH-0.4 vibrational ball mill. In some instances temperature controlled apparatus were used (58MI1); freezer/mills were used in some rare cases (13MOP1824).

The balls are made of stainless steel, agate (SiO2), zirconium oxide (ZrO2), or silicon nitride (Si3N). The use of stainless steel will contaminate the samples with steel particles and this is a problem both for solid-state NMR and for drug purity.

However, there are many types of ball mills (see Chapter 2 for more details), such as drum ball mills, jet ball mills, bead-mills, roller ball mills, vibration ball mills, and planetary ball mills, they can be grouped or classified into two types according to their rotation speed, as follows: (i) high-energy ball mills and (ii) low-energy ball mills. Table 3.1 presents characteristics and comparison between three types of ball mills (attritors, vibratory mills, planetary ball mills and roller mills) that are intensively used on MA, MD, and MM techniques.

In fact, choosing the right ball mill depends on the objectives of the process and the sort of materials (hard, brittle, ductile, etc.) that will be subjecting to the ball-milling process. For example, the characteristics and properties of those ball mills used for reduction in the particle size of the starting materials via top-down approach, or so-called mechanical milling (MM process), or for mechanically induced solid-state mixing for fabrications of composite and nanocomposite powders may differ widely from those mills used for achieving mechanically induced solid-state reaction (MISSR) between the starting reactant materials of elemental powders (MA process), or for tackling dramatic phase transformation changes on the structure of the starting materials (MD). Most of the ball mills in the market can be employed for different purposes and for preparing of wide range of new materials.

Martinez-Sanchez et al. [4] have pointed out that employing of high-energy ball mills not only contaminates the milled amorphous powders with significant volume fractions of impurities that come from milling media that move at high velocity, but it also affects the stability and crystallization properties of the formed amorphous phase. They have proved that the properties of the formed amorphous phase (Mo53Ni47) powder depends on the type of the ball-mill equipment (SPEX 8000D Mixer/Mill and Zoz Simoloter mill) used in their important investigations. This was indicated by the high contamination content of oxygen on the amorphous powders prepared by SPEX 8000D Mixer/Mill, when compared with the corresponding amorphous powders prepared by Zoz Simoloter mill. Accordingly, they have attributed the poor stabilities, indexed by the crystallization temperature of the amorphous phase formed by SPEX 8000D Mixer/Mill to the presence of foreign matter (impurities).

ball mill used in minerals processing plant | prominer (shanghai) mining technology co.,ltd

ball mill used in minerals processing plant | prominer (shanghai) mining technology co.,ltd

This ball mill is typically designed to grind mineral ores and other materials with different hardness, and it is widely used in different fields, such as ore dressing, building material field, chemical industry, etc. Due to the difference of its slurry discharging method, it is divided to two types: grid type ball mill and overflow type ball mill.

Compared with grid type ball mill, overflow type ball mill can grind materials finer even though its grinding time is usually longer. So it can make finer particle products. Hence the grid type ball mill is mainly used for primary stage of grinding while overflow type ball mill is mainly used for the secondary grinding.

Ball mill Advantages: 1Jack-up device, easy maintenance; 2The hydrostatic and hydrodynamic bearings ensure the smooth operation; 3Low speed transmission is easy for starting and maintenance; 4The oil-mist lubrication device guarantees reliable performance of bearings; 5The air clutch adopts the flexible start-up model./5According to the customer demand, manganese steel liner and wear-resistant rubber liner can be customized with good wear resistance, long service life and easy maintenance.

The grinding system uses either 'open circuit' or 'closed circuit'. In an open circuit system, the feed rate of materials is adjusted to achieve the desired fineness of the product. In a closed circuit system, coarse particles are separated from the finer ones and sent back for further grinding.

Prominer has been devoted to mineral processing industry for decades and specializes in mineral upgrading and deep processing. With expertise in the fields of mineral project development, mining, test study, engineering, technological processing.

ball mill grinding theory - crushing motion/action inside

ball mill grinding theory - crushing motion/action inside

Testing Plant Equipment:In order to determine, among other things, the operating conditions of the ball-mill when working on this rock, a test mill of about 300 T. daily capacity was erected at Duluth, Minn. The fine-crushing plant contains a Hardinge 8-ft. by 22-in. (2.4-m. by 55.8-cm.) conical mill, a 6- by 27-ft. (1.8 by 8.2-m.) Dorr duplex bowl-type classifier, a 4-ft. (1.37-m.) standard Akins classifier, and the auxiliary machinery necessary to handle the products. Each machine is driven by an individual motor, each of which is provided with meters for measuring the power required. Over 150 tests have been made in the ball-mill, varying in duration from a few hours to several weeks, in every case being continued until operating conditions became steady. The plant is so constructed that good samples of all products can be secured, both by automatic samplers and by hand. An apron feeder governs the feed rate and the tonnage is checked in every test. Water is metered into the circuit and every precaution is taken to make the data accurate and reliable.

It is a little hard to secure a basis upon which to compare crushing results. Neither Kicks nor Rittingers law of crushing is of much use in this case. This is evident when it is considered that the average size of a particle finer than 200 mesh is a matter of opinion, and that in this crushing problem practically all the ore must be crushed to pass a 200-mesh screen. The comparisons have therefore been made on the basis of kilowatt-hours per ton of material finer than 200 mesh actually produced. This, of course, does not give a scientifically exact basis for comparison, but since only the material below 200 mesh is considered finished product, in this case this is a suitable method for comparison.

On the eastern end of the Mesabi Range, in Northern Minnesota, is a large formation of siliceous rock which contains bands and fine grains of magnetite. The magnetite comprises about 35 per cent, of the rock, the remainder being chiefly quartzite and iron silicates. The rock has a specific gravity of 3.4, a hardness of 7, and is extremely tough.

This large deposit was located early in the history of the Minnesota iron-ore industry but has not been utilized because of its low percentage of iron as compared with the other Mesabi ores, and because of the difficulty and expense of any milling treatment that would concentrate the iron. An investigation, begun about 3 years ago, shows that the magnetite is finely disseminated throughout the entire formation and that there are bands or lenses of higher- and of lower-grade material, in which the magnetite and silicate are intimately mixed. As a result, the scheme of milling adopted must include a fine-crushing plant. As it is necessary to crush to 200 mesh in order to produce the desired grade of product, the fine crushing is one of the largest items of expense and for this reason has been given detailed study. It is the purpose of this paper to present some of the results of the work on fine crushing, as to both theory and practice.

Previous to fine crushing the part of the rock that contains little or no magnetite can be discarded by magnetic concentrators after each reduction in size in the dry-crushing plant. This makes it possible to fine-crush a minimum of rock and also establishes the feed to the ball-mill as below in. The fine-crushing problem, then, consists simply in crushing the rock from in. to 200 mesh at the minimum expense.

Feed rate, variable from 3 to 18 T. per hr. Ball load, 28,000 lb. of 5-, 4-, 3-, and 2-in. balls. Speed, 19.7 r.p.m. Ball-mill power, 88 kw. Feed, minus in., containing 6.52 per cent, minus 200-mesh material. Amount of solids, about 50 per cent.

Fig. 1 shows graphically that the tonnage of minus 200-mesh material produced varies directly with the tonnage fed to the mill. There is undoubtedly some limit to this relation, but there seems to be no indication of it at 18 T. per hr. Some of the conclusions drawn from this test are that: (a) The ball-mill is naturally a machine of very large capacity; (b) if it is not possible to deliver a large tonnage of original feed to the mill, a closed circuit should be provided so that the mill may crush its own oversize.

The results of these tests also are shown in Fig. 1. It is interesting to note that the curve showing tons per hour of minus 200-mesh material does not tend to flatten out as the tonnage to the mill is increased. The power per ton is also continually decreasing. It is, of course, impossible to state how much further this condition will continue, but it seems evident that it will continue for tonnages considerably beyond 15 T. per hr. As the two curves are slowly converging, at some large tonnage the amount of minus 200-mesh material produced per kilowatt-hour will be the same for either open- or closed-circuit crushing. The real advantage then gained by the closed-circuit system lies in the fact that the product consists of particles much more uniform in size. Although the average reduction in both systems may be the same, the closed-circuit will deliver a product in which the maximum-size particle will be much nearer the average size than will the open-circuit system.

(a) For equal tonnages of original feed, the closed-circuit crushing system produces the greater tonnage of minus 200-mesh material per kilowatt-hour, (b) For equal tonnages of original feed, the closed- circuit system of crushing shows the greater average reduction, (c) There is no indication that the mill was operated at, or even near, a tonnage that would give the greatest number of tons of minus 200-mesh material per kilowatt-hour. (d) Closed-circuit crushing will always have the advantage over open-circuit crushing, in that the maximum-size particle produced will be much nearer the average size. This is a desirable condition since the size of the balls making up the charge must be computed on the maximum-size particles in the feed rather than the average size.

Feed rate, 7.37 T. per hr. Ball-mill power, 108 kw. Classifier, Dorr duplex bowl-type. Feed, minus -in. ore. Ball load, 28,000 lb. of 2- and 2 3/8-in. balls. Amount of solids, about 70 per cent. Speed, 23.8 r.p.m.

There were 5.63 T. of minus 200-mesh material actually produced per hour and 19.2 kw.-hr. per ton of minus 200-mesh material produced were required. The classifier delivered 33 T. of sand per hour. The total ball-mill feed was therefore 40.37 T. per hr. or 550 per cent, of the original feed.

In the first stage, 9.11 T. of minus 200-mesh material were produced per hour and 11.98 kw.-hr. were required for each ton of minus 200-mesh material produced. The classifier delivered 32 T. of sand per hour. The total feed to the mill was therefore 47.31 T. per hr. or 308 per cent, of the original feed. The classifier overflow was reclassified, most of the material below 200 mesh being discharged from the crushing circuit while the sands were fed to the second stage. In this stage 3.73 T. of minus 200-mesh material were produced per hour and 28.9 kw.-hr. were required for each ton of minus 200-mesh material produced.

The classifier delivered 5 T. of sand per. hour. The total feed to the ball-mill was therefore 11.54 T. per hr. or 179 per cent, of the original feed. It was evident that the ball-mill was greatly underloaded in this test, but so much trouble developed in the classifier, due to the tendency of the sands to slip down the slopes, that a more rapid feed was not attempted at this time. The classifier had been set at a slope of 1 in. per ft. (125 mm. per m.) and conditions were such that the slope could not be decreased. It was impossible also to use the bowl overflow at this flat slope without rebuilding the classifier. At the present writing this work has not been completed. It seems certain, however, that the ball-mill will crush to 200 mesh a considerably greater tonnage when the proper classification is provided. Since in previous tests the mill has crushed 7 T. per hr. from in. to 200 mesh, it seems possible that it will crush at least 8 T. per hr. from 48 to 200 mesh.

Comparing single- and double-stage crushing on the basis of these two tests, it appears that the single-stage crushing produces a ton of minus 200-mesh material for 19.2 kw.-hr. while double-stage crushing produces a ton of minus 200-mesh material for 16.8 kw.-hr. These figures, though, do not show the real relative efficiencies of the two systems, for the second stage of the two-stage system was so obviously underloaded. The conclusions drawn from these tests are that (a) two-stage crushing shows a greater efficiency than single-stage, (b) two-stage crushing is much more flexible and offers greater possibilities for improvement than does single stage. In addition, a considerable amount of tailing can be discarded between the stages.

Test No. 12 shows a production of 6.3 T. of minus 200-mesh material per hour, which is 17.15 kw.-hr. per ton of this material actually produced. Test No. 150 shows a production of 8.07 T. of minus 200-mesh material per hour, which is 13.10 kw.-hr. per ton of this material actually produced. These two tests clearly indicate the superiority of small balls. It is instructive to compare the classifier sands in these two tests (see Table 0).

It appears that the small balls produced a much more uniform sand than did the large balls. The evident crowding of material at certain sizes is almost entirely absent in the small-ball test. Since this classifier sand is composed of the particles of ore that have passed through the mill at least once without being crushed, it appears that the large balls

reduce the coarse particles very readily but have trouble in crushing the finer particles. On the other hand, the small balls appear to crush all particles equally well. From this it would seem to be possible, by an analysis of the classifier sands, to determine whether or not the balls are too large or too small for the work they are doing. If the screen analysis of the sands is crowded on the upper end, the balls are too small; if it is crowded at the approximate size of the overflow, the balls are too large. The best results have been obtained when the screen analysis of the sands is about uniform between the size of the original feed and the size of the overflow.

In the tests shown in Table 9, in which balls of 2-, 2-, and 1-in. diameter (63.5, 50.8, and 38.1 mm.) were used, the tonnage also being increased, the effect of a change in speed is much more marked.

mill was unable to handle the coarse ore. The obvious conclusion is that either the speed of the mill should be increased slightly or balls of a little larger diameter should be used. At 23.8 r.p.m. the sands were nearly uniform and at this speed the mill showed the greatest efficiency.

(a) If the balls are large or the speed of the mill is high, crowding will appear at the finer sizes in the classifier sands. (b) If the balls are small or the speed is low, crowding will appear at the coarser sizes in the classifier sands. (c) The indications are that best efficiency is obtained when the screen analysis of the sands shows a minimum of crowding at any size. This statement has not been proved conclusively, however.

In view of these conclusions and the test data at hand, it is interesting to outline the manner in which a fine-crushing plant may be designed. In this discussion, the following limitations are imposed:

(a) The first cost of the plant must not be excessive. (b) Since the experiments were made with a Hardinge mill and a Dorr classifier, these are given first consideration herein, although not necessarily the best adapted for the work to be done. (c) The plant is to receive a feed and deliver a final product approximately as shown in Table 11.

The flow sheet shown in Fig. 2 has been designed to meet these requirements. Its most conspicuous feature is the large number of classifiers; possibly there are too many, but in all tests the limiting factor has been the capacity of these machines. It is estimated that the capacity of this plant will be 720 T. per day, receiving a feed and delivering a product as shown. The plant will require 344 kw. at the switchboard, which Will be 11.5 kw.-hr. per ton of ore crushed, or 14 kw.-hr. per ton of minus 200-mesh material actually produced. This is not an extremely low figure as better results have been obtained many times in the tests.

The 720 T. per day, or 30 T. per hr., of original feed will divide to the various units in the following manner: Each first-stage ball-mill will crush 15 T. per hr. to minus 48 mesh. This 15 T. will pass into the Simplex bowl-type classifier, where 10 T. will overflow as finished product; the 5 T. of sand, with the 5 T. of sand from the second Simplex bowl-type classifier, will constitute the feed to the second-stage ball-mill. The test data indicate that this can be accomplished with one classifier in closed circuit with each ball-mill. By adding the second classifier, as shown, it is expected that the tonnage can be increased at least 25 per cent. In order to maintain this feed rate, it will be necessary to maintain carefully the proper ball charge in each mill. A slight increase or decrease in the average size of the balls making up the charge will cause a large loss in efficiency and a corresponding reduction in tonnage.

If balls 3 in. (76.2 mm.) in diameter are fed to the first-stage mills and if all balls less than 2 in. (50.8 mm.) in diameter are removed from the mills regularly, the average size of the balls forming the working charge will be 2.499 in. (63.47 mm.), which is about the size indicated in the tests as giving the best results. The working ball charge in the mill will be as shown in Table 12.

Suppose that once every week the mills are stopped and all balls less than 2 in. in diameter are removed. If the ball wear is 2 lb. per ton of ore crushed, this will amount to 720 lb. (326.5 kg.) per day for each mill. This is actual wear and takes no account of the small balls that are removed. Then, since the working charge is to comprise balls from 3 in. (76.2 mm.) to 2 in. (50.8 mm.) in diameter, the amount of wear secured from each ball will be 2.89 lb. (1.31 kg.) and the 720 lb. of wear per day will be taken care of by the reduction in diameter of 249 balls per day from 3 in. to 2 in. It will then be necessary actually to charge 249 three-inch balls, or 1020 lb. (462.6 kg.) per day.

It is evident that some of the minus 2-in. balls that will be removed after seven days will be smaller than others. It may be computed by methods hereinafter described that the smallest ball will be 1.92 in. (48.7 mm.) in diameter. Then if 249 three-inch balls are charged at the beginning of each day, at the end of each day 249 balls will have been worn to a diameter of less than 2 in. At the end of seven days there will be 1743 balls of diameter between 2 and 1.92 in., which will weigh 1995 lb. (904.9 kg.) and will be removed from the mill. As the operation of each of the first-stage mills will consist in charging 249 three-inch balls each day, the mill charge will gain in weight each day until at the end of seven days it will have gained 1995 lb. and will therefore weigh 29,995 lb. At the end of the seven days, however, the 1995 lb. of balls smaller than 2 in. will be removed, leaving the original 28,000 lb. working charge, as at the beginning of the week.

Since in this flow sheet there are two first-stage mills, there will be formed 3990 lb, (1809.8 kg.) of balls per week of average diameter 1.96 in. (49.7 mm.). These 3990 balls will be used up each week in the daily charges of balls to the second-stage mill. In order to have a balanced condition, it will be necessary to charge these balls at the same rate as that at which they are made, or 498 balls per day. These 498 balls, weighing 571 lb. (259 kg.), will constitute the daily charge to the second-stage mill. This mill is to handle 240 tons of ore per day and the steel consumption at 2 lb. (0.9 kg.) per ton will be 480 lb. (217 kg.) per day. Since 498 balls, weighing 571 lb., are to be added to the mill each day, 498 balls weighing 91 lb. (41 kg.) should be removed each day. These 498 balls will weigh 0.1827 lb. (0.08 kg.) each and will be 1.06 in. (26.9 mm.) in diameter. At regular intervals all balls less than 1 in. in diameter should be removed from the second-stage mill.

If the ball charge in the second-stage mill is screened once a month, there will be 14,940 balls less than 1 in. in diameter to remove. The smallest ball will be 0.85 in. (21.59 mm.) in diameter and the largest ball will be 1 in. The total weight of the balls removed at the end of the month will be 1825 lb. (824.8 kg.). The removal of this weight of small balls will again produce the original charge that is shown in the above screen analysis. Of course, if the ball wear is not 2 lb. per ton, as assumed, these figures will not hold. However, as soon as the correct ball wear is found, it will be possible to determine by this method the exact figures that will make it possible to maintain the proper ball charge and the balance between the different mills at all times. As a result in the design of this fine-crushing plant, provision should be made for sizing the ball charges of the first-stage mills each week and of the second-stage mill each month. It can then be done with a very small amount of lost time.

The chief advantages in this flow sheet are: Good efficiency as to the power expended; large tonnage for the capital invested; and flexibility. By adjusting the overflow end of the classifier in the first stage, the load can be balanced perfectly between the two crushing stages.

In the endeavor to determine the best working conditions for the ball-mill, a detailed mathematical study was made of the action of the ball charge. While the data taken from a properly conducted test are convincing, an engineer sometimes prefers a mathematical proof. Test data contain a large personal factor, not only of manipulation but also of the person reporting the results. In the case of ball-mill crushing the amount of available data is enormous and, by careful selection, nearly any statement can be proved. For this reason, a consideration which is entirely theoretical and devoid of any personal element would seem to be desirable and instructive.

It is evident that the ball inside a revolving mill must act according to some exact regulating force which governs its every motion. There are three important variables to consider: the speed of the mill, its size, and the size of the ball charge, and it will be the aim of this discussion to show the relation existing between these variables.

Any loose charge piled up in a cone will assume a certain definite critical angle, usually called the angle of repose. If more of the charge is added to the top of the cone, this will be increased in size but the same critical angle will be maintained. This is what happens inside a mill revolving at very low speeds. The charge is tilted until the critical angle is reached, after which the balls simply roll down the slope to the lower side of the mill. This critical angle is affected but slightly by a change in the speed of the mill, up to a certain point; the increase in speed simply increases the rapidity with which the charge is raised to the top of the incline. In this condition the balls are in contact with one another except as they may bounce in rolling down the slope of the charge; also, the balls must roll down the incline at the same rate, pounds per hour, at which they are raised to the top. Then, with a mill half full of balls, any particular ball will roll down the incline something less than twice per revolution of the mill.

As the speed of the mill is slowly increased, the time required to bring the ball back to the top of the pile is diminished, but the time required by it in rolling down remains practically the same. It would seem then that the whole problem of crushing would resolve itself into getting the balls to the top of the heap fast enough. This would be true if it were not for centrifugal force and inertia. As the speed of the mill is increased these two forces grow very rapidly in importance.

Consider the forces acting on a particle p, Fig. 3, in contact with the lining of the mill. The centrifugal force c acts to press it against the lining while w1, a component of the weight w, acts to pull it away fromthe lining. Then if 1 is the angle between the vertical axis and the radius op, w1 = w cos 1. It is possible for c to be greater than, equal to, or less than w1 or w cos 1 for as 1 decreases w1 increases. Then c w cos 1 = f1, and f1 may be positive, negative or zero. If f1 is positive the particle will be held against the lining of the mill. As 1 decreases f1 decreases and if, when is zero, f1 is still positive, it is evident that the particle will maintain its contact with the mill lining throughout a complete revolution.

If f1 becomes zero for some value of 1 the particles below p1, having a greater angle , will be held against the lining of the mill by a positive force f. In other words, as the mill rotates, the force with which a particle p is held in position decreases until it reaches zero. At this point the particle is being pushed on by the particles below it and is free to move in a path governed by this initial velocity and gravity. The path it takes will, of course, be parabolic. Then when the angle is such that f is zero, the particle p will leave off contact with the mill and start on a parabolic path. In this position c = w cos .

The centrifugal force c = wv/rg, where w = weight of particle; v = initial velocity; r = radius; and g = 32.2 ft. per sec. per sec. Also the initial velocity of the particle is its velocity in the circular path, or v = 2rn in which n = speed of mill in revolutions per second. Then by substitution in the formula c = w cos ,

From this equation it is evident that an increase in either the speed of the mill or its radius will cause a decrease in the angle and the parabolic path will not start until the particle is carried farther around in the direction of rotation. At any speed n,

in which k = 1.226n. Then at constant speed, the particle p nearer the center of the circle than p1 will start on its parabolic path from a larger angle , or as r decreases increases, the relation between r and given in equation (2) always holding true when is the angle at which the parabolic path starts. Equation (2), then, is really the equation of the curve above which all particles are following the parabolic path and below which all particles are following the circular path.

From equation (1) n = g cos /4r and if the radius is considered as the constant, must decrease as n increases. Since the minimum value of is zero, when cos = 1, the speed has reached a point above which c is always greater than w cos (Fig. 3), and the particle will cling to the lining of the mill throughout the complete cycle. Then the speed at which any particle of radius r will cling is given by the equation n =g/4r in which n is in revolutions per second and r is in feet. If the speed is in revolutions per minute the equation will become

This equation shows the critical speed N at which the particle of radius r will cling to the lining of the mill or to the next outer layer of particles of radius greater than r. If N is sufficiently large, r will be sufficiently small to include all of the balls in the mill and the mill will rotate as a flywheel with no relative motion between the particles in the charge. Table 14 shows the speed at which the first particle will cling to the lining of the mill.

Below the critical speed given in equation (3), the particle of radius r will reach the critical angle a and will then start on its parabolic path. The next consideration is to determine where the particle p1 will strike the lining of the mill at the end of its parabolic path.

The simultaneous solution of these two equations will give the co-ordinates of the point d, where the two curves intersect. Substituting the value of y from the equation of the parabola in the equation of the circle and then simplifying, the following equations are secured:

These are the coordinates of the point d, at which the particle p1 will strike at the end of its parabolic path. From the above solution, it is seen that there are, in general, four points of intersection between the two curves. In this case, however, only one of these intersections requires consideration, the other three being zero. This is a very important fact, for if this condition did not exist the paths of travel of the various particles would cross and recross one another, resulting in a large friction loss above the pulp level in the mill and the performance of little or no crushing.

It is now possible to draw the outline of the charge in the mill under operating conditions. Consider an 8-ft. mill running at 24 r.p.m. From equation (2) cos = 1.226 x 24 x r/3600 = 0.1962r, which is the equation of a circle of radius 0.408/n. The center is then vertical axis 0.408/n units above the center of the mill. From this the value of in Table. 15 can be computed:

From the values of r and a, the curve aO, Fig. 5, can be drawn, which is the dividing line between the parabolic path and the circular path of the particles. Then by use of equations (4) and (5) it is possible to find any number of points on the curve cd. This may be done more simply by drawing the circle through the point e and then measuring a distance z to a vertical line which will intersect the circle at the desired point f as in Fig. 5. For this purpose, the corresponding values of x are added to the preceding table.

It is then possible to draw the line Od, which is the dividing line between the parabolic path and the circular path for all particles of the charge. The complete cycle of any particle p is then seen to be from e to f along the parabolic path, and then from f to e along the circular path. From Fig. 5 it is evident that the particle p acts exactly as though it were in a mill of radius r, the lining of which is the layer of particles of radius next larger than r.

From Fig. 5 it is evident that when a has increased beyond a certain large value, the parabolic paths of the balls near the center of the mill will overlap, thus causing interference. The balls will then be striking together at a point so near the maximum pulp level that little or no effective crushing can be done. It is thus obvious that the size of the charge should be so regulated that this interference shall not occur. It appears from Fig. 5 that this limiting condition occurs when x is a minimum, or is equal to its largest negative value.

Then since x = 4r sin a cos a r sin a, or eliminating r by use of the equation, r = g/4n cos a, x = g/n (sin a cos a sin a cos a). dx = g/n(cos4 a 3 sin a cos a cos a + sin a). For maximum and minimum values of x, dx = 0. Thus 4 cos4 a 7/2 cos2 a + = 0; whence cos a = 0.8925 and 0.2801, and a = 2649 and 7344 (7)

The larger result is obviously the one desired, the smaller one being the value that makes x a maximum. From this it appears that the largest charge that can be used in the mill without definite interference between the particles is when angle a2 = 7344 and 2 = 13112. If the inner radius of the charge, corresponding to a2 = 7344, is r2, then cos 7344 = 1.226nr2 or r2 = 0.2283/n which is the smallest value that r2 should have at any speed.

In order to determine at what angle a the maximum effective blow will be delivered by the particle when it strikes the surface of the mill, it is necessary to find the resultant velocity of the particle relative to the lining of the mill. Fig. 6 shows the resultant velocities and their components.

Vp = velocity of point on parabola; Vc = velocity of point on mill; Vt = component of Vp in direction of Ve, with mill stationary; Vm = component of VP in direction of Vc, with mill revolving; Vr = component of Vp perpendicular to Vc; = angle between Vc and VP; Vt = velocity that produces blow; or the velocity of particle relative to lining of mill.

It has been shown that the initial velocity of any particle when it started on its parabolic path is given by the equation V = rg cos a. This is the velocity in the circular path of a particle of radius r. The velocity of any point on the parabola is given by the equation

In order to determine the angle it is necessary to find the angle at which the circle and parabola intersect. This is done by computing the slopes of the tangents to both curves at this point and then the angle between these tangents. As the slope of the tangent is the first derivative of the equation of the curve, the slope of the tangent to the circle is

Thus when a = 5444 the balls are striking with maximum velocity relative to the circular path in which they travel. Since the whole charge, near ao, may be considered as being concentrated at the radius of gyration, it would seem that the most effective conditions would be obtained by placing r (equation 9) equal to the radius of gyration of the charge. Since the radius of gyration is equal to r1 + r2/2 when r1 is the radius of the mill and r2 is the inner radius of the charge, then

The value of K given by this equation is the relation between r1 and r2 which should exist for best operating conditions and is really the measure of the quantity of the charge. This equation then gives the proper relation between the size of the charge, the size of the mill and its speed. It is the fundamental equation of the ball-mill and shows the relations mentioned on page 264.

Equations (12) to (16) all depend on the value of K, which is the real measure of the quantity of the charge. It is now necessary to get a better idea of the exact relation between K and the volume of the charge. In order to do this the cycle of the charge must be known.

This means that when the mill is running at the proper speed for the ball charge, then the charge is passing through 1.444 cycles per revolution, and each ball in the charge strikes, on the average, 1.444 blows per revolution.

Equation (18) states that the balls spend 56.65 per cent, of the time in the circular path. Then it is apparent that 56.65 per cent, of the total charge is always in the circular path. In other words, the volume of the charge between r1 and r2 (Fig. 5) is only 56.65 per cent, of the total charge, the remaining 43.35 per cent, being spread out over the rest of the mill and following the parabolic path.

The exact analytical determination of the variation in the volume of the total charge as K varies is very complicated and will not be gone into here. A very close approximation can be made, however, by use of the equation,

in which P is the fractional part of the entire volume of the mill that is occupied by the charge when the mill is stationary. It should be noted that the charge will contain a considerable proportion of voids. These are, of course, included in the space occupied by the charge.

From equation (8) it appears that Vb = 16kgr 32kgr4 + 16k5gr6, but the kinetic energy e = wv/2g, or in this case, e = w(8kr 16k3r4 + 8k5r6), which is the energy possessed by any particle of weight w, and radius r, at the end of its parabolic path, which is available for the purpose of crushing ore. Then the total energy possessed by the particles of radius between r1 and r2 is expressed by the equation,

In this equation, if W is the entire weight of the charge, then E represents the foot-pounds of energy delivered each time the charge passes through one cycle. Then since there are 1.444 cycles per revolution, and n = 0.8158/r1 41 + k rev. per sec., the number of foot-pounds per second is represented by the equation,

This formula gives the power output and therefore input to the mill when the weight of the charge is W, in pounds, the radius of the mill is r1, in feet, and the value of K and the speed N are as given by formulas (20) and (13). In other words, formula (22) gives the power required to operate the mill at the most efficient speed for any ball charge. In Table 16 the horsepower required has been computed for certain operating conditions: Any table or set of curves covering all conditions would be too large and complicated to include in this paper; the formulas may, however, be applied to any particular condition.

The actual application of the formulas to a definite problem may be instructive. Consider an 8 by 6-ft. cylindrical mill charged with 28,000 lb. (12,700 kg.) of steel balls. If the balls are made of steel weighing 500 lb. per cu. ft., and are all of one size, it may be shown that the charge will weigh 74.05 per cent, of 500 lb., or 370.25 lb. per cu. ft. The charge will then occupy 28,000 370.25 = 75.6 cu. ft. (2.14 cu. m.) of space in the mill. The factor 75.05 per cent, is derived on the assumption that the spheres are equal; in the case of a mill, the space being limited and the balls not of one size, 65 per cent, is probably more nearly correct. Using this factor, the charge would weigh 325 lb. per cu. ft., and would therefore occupy 86 cu. ft. (2.23 cu. m.). The volume of an 8 by 6-ft. mill is 301 cu. ft. (8.5 cu. m.), hence the charge occupies 28.6 per cent, of the total volume. From formula (20), when the charge occupies 28.6 per cent, of the volume of the mill, the factor K is 0.770. The speed of the mill, by formula (13), is 21.75 r.p.m., and the power, by formula (22), is 181.5 hp. Angle a will then be given by formula (15):

From these results and formula (2), which gives other values of r for various values of a, it is possible to plot the outline of the charge, as is shown in Fig. 7. The particular path of any ball can be plotted by use of equation (3a).

r = radius to any particle p. r1 = radius of mill. r2 = inner radius of charge. R = radius of gyration of charge near ao. a = angle from vertical to r. a1 = angle from vertical to r1 a2 = angle from vertical to r2. ar = angle from vertical to R. = angle from horizontal to r. 1 = angle from horizontal to r1. 2 = angle from horizontal to r2. n = speed of mill in rev. per sec. N = speed of mill in rev. per min. N1 = critical speed of mill in rev. per min. Vb = relative velocity of particle at od, ft. per sec. w = weight of portion of charge, lb. W = weight of entire charge, lb. P = fraction of mill volume occupied by charge. g = a constant = 32.2 ft. per sec. per sec. k = a constant = 4n/g = 1.226n. K = a constant = r2/r1 H = height of charge in mill at rest. E = kinetic energy, foot-pounds. Cn = cycles per revolution. re = radius of circle oa.

By use of these equations, with any given set of conditions, it is possible to determine the geometrical shape of the charge in the mill, the horsepower absorbed by it, the velocity of the blow struck by any ball, and the number of blows struck by any ball. The equations show also the relation that should exist between speed, diameter of mill and size of charge in order to secure the maximum theoretical efficiency.

In order to observe how closely theory and practice agree, a small model mill 3 in. (76.2 mm.) in diameter and 2 in. (50.8 mm.) long was made, having a bearing at only one end so that the other could be closed by a piece of glass through which the action of the charge could be observed. The method of comparison consisted in introducing a weighed charge of fine sand, computing the best operating speed, and drawing the outline of the charge according to the preceding theory. The mill was then operated at this speed, and photographed. The comparison between the photograph and the drawing shows how closely theory and practice agree. No accurate data as to the power required could be secured on this small model. A number of these photographs and the corresponding drawings are shown.

The similarity between the photograph of the mill in actual operation and the theoretical drawing is very striking, especially when, the mill contains a large charge. When the charge is small, the difference appears greater; this is because all interference between the particles causes them to fall into the open space near the center of the mill. The photographs could not be made to show clearly the fact that these particles were accidental; it is apparent, however, when actually watching the mill run, that the particles in the central space are only occasional, as compared with the outer band. While the results of interference are more evident in the small charge than in the large one, the actual amount of interference is greater in the large charge than in the small. This is evident when the cause of this interference is considered.

The curve a-b (Fig. 5) shows the boundary line between the circular and the parabolic paths. Each particle, as it passes the line a-b, starts on its parabolic path in a direction perpendicular to the radius of the

mill through that point. It is evident that the perpendicular to the radius at p would intersect the perpendicular to the radius at a if it were produced far enough. If the two particles considered are closer together than a and p on the curve a-b, the intersection between the lines of initial direction are closer to the points considered. If the two points are adjacent on the curve a-b, it is apparent that the intersection will be

very close to the points and will, in fact, take the form of a slight crowding action between the particles. The result of this will be a slight deformation of the curve through which the particle travels. This will be just as prominent in a small charge as in a large one, although the results will be more apparent in the small charge.

It may also be shown that when the size of the charge exceeds 0.4 the volume of the mill, there will be a tendency for the particles near the center of the mass to crowd one another. This is, however, not at all serious and could probably never be detected in operation, but as previously stated, when the mill is filled beyond 0.64 of its volume, the interference becomes quite important and the mill probably could not be made to operate efficiently when more than 0.6 full.

It appears from the photographs that there is a certain amount of movement between the particles at the end of the parabolic path which causes the actual parabolic path to end sooner than the theoretical path. This motion between the particles is due to the fact that each particle must change its direction of travel and move at about right angles to its original path. This change in direction requires time and reacting forces; if the force is small the time will be long and the agitation great. If the force is large the time will be small and the agitation small. Therefore, when the mill speed is low, this zone of agitation is wide, as shown in Fig. 14. In this agitation zone grinding is done by attrition, but above it, the crushing is done by impact.

While these photographs and drawings were made to illustrate the action of the particles in the charge of a 3-in. mill, they also show the action in mills of any size when operated at the most efficient speed, as given by formula (13). In Table 17, the speeds have been computed for various sizes of mills and charges. In each case, the illustration that shows the position of the charge for the particular operating condition is indicated

In Figs. 14, 15, 16 and 17, the effects of high and low speeds are shown. In all of these photographs the mill was 0.4 full, the operation at the proper speed being shown in Fig. 11. Table 18 shows the speed at which the charge in mills of various diameters would appear as illustrated.

In this whole discussion, only the force of gravity and centrifugal force have been considered. In a mill containing water and ore as well as balls, the force of adhesion is to be considered. This force not only tends to hold the balls and ore together but also tends to hold them against the lining of the mill. Just how important this force may be under ordinary operating conditions is hard to say. It was shown, however, in the little model mill, that adhesion tended to hold the particles together in their parabolic paths and almost entirely eliminated the accidental particles that fall near the center of the mass. It is impossible to apply the results secured in a small mill to a large mill in this respect, however, as adhesion varies inversely with the size of the particles considered.

Adhesion also varies with the moisture, so the mill operator has a convenient means of controlling this force so as to produce the best results. The amount of moisture in the pulp for best efficiency will vary with the nature of the ore, the nature of the ball charge, and the nature of the mill. With a mill charge of large steel balls, adhesion will not affect the operating conditions to any considerable extent unless the pulp is made very thick. The tendency would then be for the balls to stick to the lining and revolve with it.

It is very important to prevent slipping between the charge and the lining of the mill; the tendency to slip is much smaller with large charges than with small ones. If the friction between the charge and the lining of the mill is not great enough to carry the particles up to the curve a-b, the efficiency of the mill will be very greatly reduced and the lining of the mill will be rapidly worn away. Flat sides will also appear on the balls and the cycle of the charge will be slow and irregular. In an open-trunnion discharge mill, the pulp will not flow from the mill regularly but will come in pulsations. Lifters or roughened liners are therefore desirable, as they insure a greater coefficient of friction.

A. L. Blomfield, Colorado Springs, Colo, (written discussion). I congratulate the author on bringing out a paper of real service to the profession. His contention of uniform size in balls is borne out by my own experience; in coarse crushing at the Golden Cycle in 6 by 6-ft. (1.8 by 1.8-m.) ball-mills we unquestionably gain by screening out the small balls once or twice a month. The point of gaging the ball size to be used by the uniformity of screen sizing is of particular interest.

The necessity of sufficient return feed from classifier to the ball-mill is sound and clearly shown. In connection with this, I wish two further points had been gone into as thoroughly: (1) The effect of the quality of classification. In general, it is true that the smaller the per cent, of undersize in the feed the more effective is the mills work. This is true on a bucking board, in tube-mills, ball-mills, and grinding pans. Given the possibility of returning a full-feed load to any mill, it has been my experience that the effective work in the grinder is almost proportional to the quality of the return feed. (2) Again speaking generally, the shorter the tube-mill the greater is the quantity of return feed necessary to keep it loaded. The classification thus keeps the oversize in the mill more free from finished product and thus the crushing more efficient. It is very easy to overload any long mill with too much return feed. The authors tests were made on an 8-ft. by 22-in. Hardinge. This type is capable of handling very large return feeds. I would like to hear Mr. Davis views on the best length of mill, given the diameter.

Dealing with feeds to fine grinders: At the mill of the Great Fingall Cons. M. Co., in 1906, we found that the 5-ft. grinding pan gave the greatest tonnage in closed circuit, grinding a feed 8+20 mesh to 20 mesh when the feed was slightly over twice the effective work done, and that the effective work was almost directly proportional to the efficiency of classification.

I note the large number of classifiers in his flow sheet and agree that it is clearly demonstrated that sufficient classifier capacity should be installed, as they cost very little to run. Two 6-ft. classifiers to the ball-mill could probably be replaced by one 12-ft. quadruplex machine, though possibly the only gain would be a saving in first cost.

H. A. White, P. O. Dersley, Transvaal (written discussion). The fact that the author makes no reference to the work of others on the same subject, I think, must be attributed to the neglect of the usual distinction between ball and tube mills, which is founded upon the presence of special lifting devices in the ball mill. The paper really deals with tube-mill theory, upon which quite a lot of work has been done. The most accessible reference will probably be Richards Ore Dressing, (Vol. III, p. 1336), but I will specially refer to my own papers in the Journal of the Chemical, Metallurgical & Mining Society of South Africa (Vol. V, p. 290 and Vol. XV, p. 176), where very much the same ground is covered.

It may be interesting to compare the results obtained by an independent handling of the same problem. The critical speed obtained is very, slightly different owing to the value of g, which, of course, is not everywhere the same, author has omitted to note the fact that his diameter of mill must be reduced by the average diameter of balls used in order to make the theoretical particle correspond with the actual balls and, of course, only the inside diameter of the lined tube is meant.

The directions for drawing the parabolic curve of flight might be very much simplified by using the relation between the angle of impact and the angle of departure, which I discovered in 1905 and the author has proved on p. 269. The author notes that the locus of points of departure is a semicircle but does not observe that the locus of points of impact is a trisectrix. The maximum of x, when only one layer of balls is considered (the outside layer), is obviously r and the angle of departure is 30 from the vertical.

In order to calculate the maximum value of the blow struck, the author uses the second order effects beside the principal one due to the height of fall of the balls from the vertex of the parabola. The author thus derives a value of 0.5775 for cos a, this value is identical with that found for the maximum height of fall, as might have been anticipated, but the derivation of the latter is very much simpler. He does not notice that the path in this case is through the center of the mill.

The author deviates from exact methods and uses the idea of center of gyration in place of summation of various layers of balls and no doubt the approximation is sufficiently close if K were independently known; but to ascertain K the assumption is made that the average of the whole charge passes through the same cycle as the particle at the radius of gyration, and as the inner layers have a much shorter cyclic time than the outer and there are also many fewer balls, this assumption is much less accurate. In fact, the authors figure of average number of cycles per revolution (1.444) may vary from more than 1.5 to less than 1.2, in accordance with the speed and loading of the tube. However, if correction is made of tube diameter, as previously mentioned, the final results are not very far out.

Of importance is the question of maximum efficiency to be got out of any tube and the load for that efficiency; but though the author gives the best speed for any load he does not indicate which load and speed give maximum efficiency. A further important question in actual running plants is the maximum capacity that may be gotten out of any tube, and as the efficiency is not widely affected this latter maximum may be the most important. These points may be well illustrated from the Witwatersrand practice with standard tube mills 5 ft. 6 in. by 22 ft. The effective diameter inside linings, allowing 2 in. for pebbles used is put at 59 in. and the speed for maximum efficiency is 27.96 r.p.m. with a load about 45 per cent., while the maximum capacity is attained at 32.2 r.p.m. with a load 3 in. above the center.

These theoretical deductions and some others of interest were confirmed by observation of a working model of 7 ft. diameter, the full account of which will be found in the papers mentioned. I have to thank the author for the exceedingly clear manner in which his paper is arranged and for the able paragraphs on ball wear which should be of great practical use.

ball mill: operating principles, components, uses, advantages and

ball mill: operating principles, components, uses, advantages and

A ball mill also known as pebble mill or tumbling mill is a milling machine that consists of a hallow cylinder containing balls; mounted on a metallic frame such that it can be rotated along its longitudinal axis. The balls which could be of different diameter occupy 30 50 % of the mill volume and its size depends on the feed and mill size. The large balls tend to break down the coarse feed materials and the smaller balls help to form fine product by reducing void spaces between the balls. Ball mills grind material by impact and attrition.

Several types of ball mills exist. They differ to an extent in their operating principle. They also differ in their maximum capacity of the milling vessel, ranging from 0.010 liters for planetary ball mills, mixer mills, or vibration ball mills to several 100 liters for horizontal rolling ball mills.

Im grateful for the information about using a ball mill for pharmaceutical products as it produces very fine powder. My friend is working for a pharmaceutical company and this is a good article to share with her. Its good to know that ball mills are suitable for milling toxic materials since they can be used in a completely enclosed for. Thanks for the tips!

grinding media - milling balls - ceramic grinding media | norstone inc

grinding media - milling balls - ceramic grinding media | norstone inc

Grinding Media Grinding media are the means used to crush or grind material in a mill. It comes in different forms such as alumina oxide balls, ceramic cylinders, or soda lime glass. At Norstone Inc., we offer all types of medias used for grinding, deagglomeration, polishing, deburring, fillers, proppants, spacers, refractory beds and shot peening. Below, youll find a variety of ceramic grinding media specifically formulated to ensure reliable, consistent performance for your bulk material preparation. We also offer technical expertise on current and expanded uses for these medias; Call us to ensure that you are using the right media for your current product and process! Our specialists will recommend the best suited media, shape, size and alloy. The choice of media can depend upon the material to be ground, the grinding process, and the wear mechanisms involved. Toll/Screening services are available for sizing worn media.

Non-abrasive, cube shape, high chemical resistance, non-toxic, dust free. Smallest size available is 0.5mm x 0.5mm x 0.87mm diagonal. Density: 1.20 gm/cc. Bulk Density: 0.68 kg/l; 1.50 #/l; 2.50 kg/gal; 5.50 #/gal

Non-abrasive, spherical in shape, non-toxic and dust free. A variety of levels of cross linked polymers are available in sizes as small as 100 microns. Low in density but tough and wear resistant. Standard and Toughened Polystyrene beads have a strong odor from free styrene but this can be eliminated with a warm water wash. Also available in food grade, porous, toughened and narrow particle distributions. Density: 1.05 gm/cc. Bulk Density: 0.63 kg/l; 1.40 #/l; 2.30 kg/gal; 5.00 #/gal

Non-abrasive, spherical in shape, non-toxic, no odor and dust free. Available in sizes under 150 microns. Not solvent resistant. Density: 1.05 gm/cc. Bulk Density: 0.63 kg/l; 1.40 #/l; 2.30 kg/gal; 5.00 #/gal

Smallest size available is 2.0 mm. Good solvent resistance. Can swell with use in water. Nylon also stains if used with pigments. Density: 1.13 gm/cc. Bulk Density: 0.68 kg/l; 1.50 #/l; 2.50 kg/gal; 5.50 #/gal

High density, non-toxic balls used for delumping, mixing and blending of powders. Certain sizes are available with steel cores. Very long wearing and gentle on the mill. Density: 1.20 gm/cc. Bulk Density: 0.72 kg/l; 1.60 #/l; 2.60 kg/gal; 5.80 #/gal.

High density, non-toxic balls used for delumping, mixing and blending of powders. Certain sizes are available with steel cores. Very long wearing and gentle on the mill. Density: 1.20 gm/cc. Bulk Density: 0.72 kg/l; 1.60 #/l; 2.60 kg/gal; 5.80 #/gal.

This media is still used because of its low price but can be costly in the long run. It is abrasive to the mill due to its irregular shape as it is more needle-like than spherical and the tips tend to break off. Waste disposal of this short term media can also be expensive. Alternative medias are glass and mullite. Density: 2.50 gm/cc. Bulk Density: 1.50 kg/l; 3.30 #/l; 5.50 kg/gal; 120 #/gal

This is the most popular glass sphere used for grinding media. The larger beads are molded. Some brands are produced from virgin glass while others are produced from recycled glass. Air inclusions also vary which can determine the life span of the bead as it determines the strength of the bead. This is an excellent bead for low viscosity material or low heat processes. Density 2.50 gm/cc. Bulk Density: 1.50 kg/l; 3.30 #/l.; 5.50 kg/gal; 12.00 #/gal

This is the most popular glass sphere used for grinding media. The larger beads are molded. Some brands are produced from virgin glass while others are produced from recycled glass. Air inclusions also vary which can determine the life span of the bead as it determines the strength of the bead. This is an excellent bead for low viscosity material or low heat processes. Density 2.50 gm/cc. Bulk Density: 1.50 kg/l; 3.30 #/l.; 5.50 kg/gal; 12.00 #/gal

There are several grades of borosilicate glass beads. This bead is used for low alkali applications as well as food and pharmaceutical. There is also a high crush strength bead which is more abrasion resistant than the soda lime glass. It is more expensive than the soda lime but the value is there. Density 2.60 gm/cc. Bulk Density: 1.60 kg/l; 3.50 #/l.; 6.00 kg/gal; 13.30 #/gal

A natural resource that is getting harder to find in its natural state. It is basically quartz having similar density to glass but harder with irregular shapes and surfaces. The benefit of the pebble is the aspect ratio thus giving it a lot of surface area for contact in the mill. They are still available but getting to be expensive. A good alternative is Steatite. Density: 2.60 gm/cc. Bulk Density: 1.60 kg/l; 3.50 #/l; 6.00 kg/gal; 13.30 #/gal

This media is a fused magnesium silicate composite made up of 62% SiO2. The minimum size is 6.0 mm available in satellite balls, cylinders and spheres. This is an excellent alternative to flint pebbles or large glass balls. It lasts longer than glass but is the same density. Density 2.60 gm/cc. Bulk Density: 1.60 kg/l; 3.50 #/l; 6.00 kg/gal; 13.30 #/gal

Generally available in 92% and higher, balls tend to have less wear issues than satellites. Balls & satellites are much easier to use than cylinders and are commonly found in liquid grinding applications. Density: 3.60 gm/cc. Bulk Density: 2.20 kg/l; 4.90 #/l; 8.20 kg/gal; 18.00 #/gal

Available in percentages of 92% and lower. They are easier to use than cylinders and one of the most popular medias for ball milling. Density: 3.60 gm/cc. Bulk Density: 2.20 kg/l; 4.90 #/l; 8.20 kg/gal; 18.00 #/gal

Available in the same alumina percentages as balls and satellites but larger sizes are more limited in options. Cylinders are used for both liquid and powder processing when fines are needed. They can also be susceptible to chipping around the edges. Density: 3.60 gm/cc. Bulk Density: 2.20 kg/l; 4.90 #/l; 8.20 kg/gal; 18.00 #/gal

This is still the most common range of alumina media used for particle size reduction in both powder and liquid grinding. Beads are available as well as balls, satellites and cylinders. Some sizes are available in both dry pressed and iso pressed. The beads can be abrasive. Density: 3.60 gm/cc. Bulk Density: 2.20 kg/l; 4.90 #/l; 8.20 kg/gal; 19.00 #/gal.

Alumina with this higher purity is used in grinding materials which cannot tolerate contamination other than alumina. It can be dramatically more expensive and is also more brittle than other alumina formulations. It is available in spheres, satellites and cylinders. Density: 3.80 gm/cc. Bulk Density: 2.40 kg/l; 5.30 #/l; 8.60 kg/gal; 19.00 #/gal.

This is a low density ceramic available in limited sizes. The balls and satellites are usually custom made. It is very expensive but used where limited contamination is required. Density: 2.90/3.20 gm/cc.

This is a low density ceramic available in limited sizes. The balls and satellites are usually custom made. It is very expensive but used where limited contamination is required. Density: 2.90/3.20 gm/cc.

This alumina media is most often referred to as MULLITE with approximately 35% SiO2. It has the advantage of being higher in density than glass and lower density than other aluminas. Beads are available in several different alumina concentrations and densities, with or without bauxite. It is available in small beads, satellites and cylinders. It lasts longer than glass and is not as abrasive as other aluminas. Density: 3.25 gm/cc. Bulk Density: 1.74 kg/l; 3.80 #/l; 6.70 kg/gal; 14.50 #/gal

This bead is also a popular medium density bead which looks almost identical to the Zirconia Silicate but they can NEVER be mixed. This bead is FUSED and is consistent from the crust to the core. It lasts longer than a sintered bead but should not be used in sizes above 2.0 mm because of the inherent air inclusions known as hollows in the bead. This bead can crack and break and cause abrasion problems in the mill. Preconditioning the beads is strongly recommended. Density: 3.80 gm/cc. Bulk Density: 2.40 kg/l; 5.00 #/l; 8.60 kg/gal; 19.00 #/gal

This is a popular, medium density, bead which is SINTERED. This bead has a hard outer crust and a soft inner core so it should be used in less aggressive types of small media mills. Sizes above 3.0 mm are not practical because of the inherent structure which weakens the bead and causes it to crack and break. This bead can be abrasive to the mill. Density: 4.00 gm/cc. Bulk Density: 2.45 kg/l; 5.30 #/l; 9.27 kg/gal; 20.40 #/gal.

Zirconia Toughened Alumina: This product is relatively new and has proven to be an excellent media in the medium density range. It is solid, white, round, has high fracture resistance with lower amounts of zirconia and no radioactivity. Sizes start at 0.6 mm and can be made up to 2 in balls and cylinders. Density: 4.20 gm/cc Bulk Density: 2.60 kg/l; 5.70 #/l; 9.60 kg/gal; 21.00 #/gal.

This is a relatively new bead which is aFUSED zirconia silica containing a higher amount of zirconia than the more common formulation. Customers have been impressed with its ability to last much longer than standard zirconia silica and silicate, its lower wear on the equipment and faster grinds. Density: 4.60 gm/cc. Bulk Density: 2.80 kg/l; 10.60 kg/gal; 23.30 #/gal; 6.20 #/l.

A very popular high density ceramic satellite or cylinder for all types of milling. While this form of the media is excellent, the bead is very poor in that it is abrasive to both the mill and itself. Density: 5.50 gm/cc. Bulk Density: 3.20 kg/l; 7.00 #/l; 11.80 kg/gal; 26.00 #/gal

A very popular high density ceramic satellite or cylinder for all types of milling. While this form of the media is excellent, the bead is very poor in that it is abrasive to both the mill and itself. Density: 5.50 gm/cc. Bulk Density: 3.20 kg/l; 7.00 #/l; 11.80 kg/gal; 26.00 #/gal

A very popular high density ceramic satellite or cylinder for all types of milling. While this form of the media is excellent, the bead is very poor in that it is abrasive to both the mill and itself. Density: 5.50 gm/cc. Bulk Density: 3.20 kg/l; 7.00 #/l; 11.80 kg/gal; 26.00 #/gal

This is a relatively new high density mediathat has grown in popularitydue to its durability and value pricing. The bead will not crackor break unless the mill was not put together properly. The media is available in beads, satellites, cylinders and spheres. Density: 6.00/6.25 gm/cc. Bulk Density: 3.60/4.00 kg/l; 7.90/8.80 #/l; 12.70/15.10 kg/gal; 28.00/33.00 #/gal

This is a relatively new high density mediathat has grown in popularitydue to its durability and value pricing. The bead will not crackor break unless the mill was not put together properly. The media is available in beads, satellites, cylinders and spheres. Density: 6.20 gm/cc. Bulk Density: 3.60/4.00 kg/l; 7.90/8.80 #/l; 12.70/15.10 kg/gal; 28.00/33.00 #/gal

This is a relatively new high density mediathat has grown in popularitydue to its durability and value pricing. The bead will not crackor break unless the mill was not put together properly. The media is available in beads, satellites, cylinders and spheres. Density: 6.00/6.25 gm/cc. Bulk Density: 3.60/4.00 kg/l; 7.90/8.80 #/l; 12.70/15.10 kg/gal; 28.00/33.00 #/gal

This is the highest, longest lasting and toughest high density media. This media is very hard and non-porous so that it will not break or crack, cleans easily, and is available in several grades. Beads, spheres and cylinders are available in a wide range of sizes. Density: 6.00 gm/cc. Bulk Density: 3.70 kg/l; 8.10 #/l; 14.00 kg/gal; 30.10 #/gal

This is the highest, longest lasting and toughest high density media. This media is very hard and non-porous so that it will not break or crack, cleans easily, and is available in several grades. Beads, spheres and cylinders are available in a wide range of sizes. Density: 6.00 gm/cc. Bulk Density: 3.70 kg/l; 8.10 #/l; 14.00 kg/gal; 30.10 #/gal

This is the highest, longest lasting and toughest high density media. This media is very hard and non-porous so that it will not break or crack, cleans easily, and is available in several grades. Beads, spheres and cylinders are available in a wide range of sizes. Density: 6.00 gm/cc. Bulk Density: 3.70 kg/l; 8.10 #/l; 14.00 kg/gal; 30.10 #/gal

Case and through hardened steel balls which can rust. They are available in a wide range of alloys and sizes as large as 8" diameters. Density: 7.60 gm/cc. Bulk Density: 4.50 kg/l; 9.90 #/l; 17.80 kg/gal; 38.00 #/gal

This is a through hardened chrome alloy steel ball. It is highly polished and mono-sized with a hardness of 63-65 Rockwell C. The pricing is reasonable for an almost ball bearing quality media. It is slow to rust and is a long lasting steel media. Density: 7.60 gm/cc. Bulk Density: 4.50 kg/l; 9.90 #/l; 17.80 kg/gal; 38.00 #/gal

Through hardened carbon steel balls that have a flat 180 degrees apart. They are commonly used in steel ball mills starting at 1/2" diameter. They can rust. Density: 7.60 gm/cc. Bulk Density: 4.50 kg/l; 9.90 #/l; 17.80 kg/gal; 38.00 #/gal

Through hardened balls which are available in various types of stainless. These balls can be expensive but generally used when other types are not acceptable. Stainless steel is softer than other forms of steel. It can also work harden and become brittle. Density: 7.60 gm/cc. Bulk Density: 4.50 kg/l; 9.90 #/l; 17.80 kg/gal; 38.00 #/gal

This is cut wire which can then be used as cylinders or conditioned so that it is somewhat round in shape. It is available in various types of stainless. Stainless steel is softer than other forms of steel. It can also work harden and become brittle. Density: 7.60 gm/cc. Bulk Density: 4.50 kg/l; 9.90 #/l; 17.80 kg/gal; 38.00 #/gal

Not typically a popular media but still available. Stainless steel is softer than other forms of steel. It can also work harden and become brittle. Density: 7.60 gm/cc. Bulk Density: 4.50 kg/l; 9.90 #/l; 17.80 kg/gal; 38.00 #/gal

There are many sources for steel shot but all are not equal since much of the steel shot is used for shot peening. Make sure that the shot is designed as a grinding media or it could tear up the mill. Steel shot is one of the least expensive grinding medias with the benefit of high density and the availability of a wide range of sizes for small media. The more narrow size ranges of shot will last longer. Density: 7.60 gm/cc. Bulk Density: 4.50 kg/l; 9.90 #/l; 17.80 kg/gal; 38.00 #/gal

This media continues to grow in interest due to its high density. Beads and satellites are available in limited sizes. The mills using this media must be built to handle the high density. Density: 15.00 gm/cc. Bulk Density: 8.20 kg/l; 18.00 #/l; 30.00 kg/gal; 66.00 #/gal

This media continues to grow in interest due to its high density. Beads and satellites are available in limited sizes. The mills using this media must be built to handle the high density. Density: 15.00 gm/cc. Bulk Density: 8.20 kg/l; 18.00 #/l; 30.00 kg/gal; 66.00 #/gal

NORSTONE, INC. PRIVACY POLICY Grinding Media Depot , Blade Depot, Deco Bead Depot and Polyblade-Norblade are Registered Trademarks of Norstone, Inc. Polyblade Patent No. 5,888,440 and Patent No. 8,028,944 B2

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